In Comics
Detective Comics #33 - The Batman Wars Against The Dirigible Of Doom
  
Web of Spider-Man #18 - The Longest Road
  
Relatives
Not Available
  
Carl Brock (father, estranged), Janine Brock (mother, deceased), Mary Brock (sister), Ann Weying (ex-wife, deceased), Symbiotes relatives: Toxin Symbiote (current symbiote, former grandson), Venom Symbiote (former symbiote, grandfather, former brother), Agony, Phage, Riot, Lasher (uncles, former sons), Scorn (sister, former niece), Carnage (father, former son), Scream (aunt, former daughter, deceased), Hybrid (uncle, former son, deceased)