Alias
The Prince of Puzzlers, Edward E. Nygma, Mr. E.Nigma, The Crown, Prince of Conundrums & Wizard of Quiz
  
Mac Gargan, Venom Spider-Man, Sinister Spider-Man, Arachnid, Kilgore Trout, Venorpion, Skorpion, Scorpius
  
In Films
Frank Gorshin, Jim Carrey
  
Not Yet Appeared