In Comics
Web of Spider-Man #18 - The Longest Road
Superman Vol 2 #160 (September, 2000)
Relatives
Carl Brock (father, estranged), Janine Brock (mother, deceased), Mary Brock (sister), Ann Weying (ex-wife, deceased), Symbiotes relatives: Toxin Symbiote (current symbiote, former grandson), Venom Symbiote (former symbiote, grandfather, former brother), Agony, Phage, Riot, Lasher (uncles, former sons), Scorn (sister, former niece), Carnage (father, former son), Scream (aunt, former daughter, deceased), Hybrid (uncle, former son, deceased)
Bizarro-Lois No. 1 (wife, Pre-Crisis only), Bizarro, Jr. (son, Pre-Crisis only), Bizarro-Lois, Jr.