In Comics
Web of Spider-Man #18 - The Longest Road
Fantastic Four Annual #6 (November, 1968)
Relatives
Carl Brock (father, estranged), Janine Brock (mother, deceased), Mary Brock (sister), Ann Weying (ex-wife, deceased), Symbiotes relatives: Toxin Symbiote (current symbiote, former grandson), Venom Symbiote (former symbiote, grandfather, former brother), Agony, Phage, Riot, Lasher (uncles, former sons), Scorn (sister, former niece), Carnage (father, former son), Scream (aunt, former daughter, deceased), Hybrid (uncle, former son, deceased)
Annihilus is a series of clonal scions